SYNTHESIS AND STUDYING OF APPLICATIONS IN (COORDINATION ,CHROMATOGRAPHY ,CHEMICAL MEASUREMENTS) OF HEXA-DENTATE LIGANDS IN THE COMPLEXES
Abstract
Abstract :
Our studying involved , synthesis of new two ligands   containing six – chalet in same ligand  and six – donor and their complexes with zinc  ion Zn (II) ., all reactions included azotation reaction , imination reaction , coupling reaction.
The formatted ligands and their complexes were identified  by (I.R ,UV–Vis , H.NMR ) ,molar conductance and melting points , chromatographic studying and other physical studying. The two ligands appeared good indicators and their complexes through many studies for determination of optimal conditions of complexation with mole ratio (M:L ) (1 : 1) and the ligand ( L1 ) and ligand (L2) gave   octahedral shape via  six – atoms donor.
Keywords : import , atom , coord .