AUTHENTICATION OF GRAPE SEED FACE OIL USING FTIR SPECTROSCOPY COMBINED WITH CHEMOMETRICS TECHNIQUES

Andi  Prayoga; Anjar Windarsih; Wuri  Apriyana; Florentinus Dika Octa Riswanto; Enade Perdana Istyastono

doi:10.22159/ijap.2024v16i5.51525

Authors

Andi Prayoga
Anjar Windarsih
Wuri Apriyana
Florentinus Dika Octa Riswanto Faculty of Pharmacy Universitas Sanata Dharma http://orcid.org/0000-0002-7174-6382
Enade Perdana Istyastono

DOI:

https://doi.org/10.22159/ijap.2024v16i5.51525

Keywords:

grape seed oil, face oil, adulteration, FTIR spectroscopy, chemometrics

Abstract

Objective: This research aims to authenticate grape seed oil products using FTIR spectroscopy combined with chemometric methods.

Methods: In the initial stage, exploratory data analysis was carried out by applying the main components with the Principal Component Analysis (PCA) model. Second derivative spectra resulting from preprocessing of the original spectra are used to create multivariate Principal Component Regression (PCR) and Partial Least Squares (PLS) calibration models. The second derivative spectra of GO, OO, and the binary mixture GO+OO are utilized to generate a sparse partial least squares-discriminant analysis (SPLS-DA) model.

Results: The PCA model was successfully obtained with visualization that depicted a total of 93.8% in the first and second dimensions. Multivariate calibration produced the best model in PLS with second derivative spectra for both GO and OO. The SPLS-DA model was successfully built and discriminated with AUC-ROC values of 1,000, 1,000, and 0.994 for GO, OO, and GO+OO, respectively.

Conclusion: Authentication of grape seed face oil can be undertaken using FTIR spectroscopic methods and chemometric techniques, which can produce high sensitivity and specificity values.

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References

Barros C, Barros RBG. Natural and Organic Cosmetics: Definition and Concepts. J Cosmetol Trichology. 2020;6(2):1–9. 10.4172/2471-9323.1000143

Mursyidi A. The Role of Chemical Analysis in the Halal Authentication of Food and Pharmaceutical Products. JFood PharmSci. 2013;1(2013):1–4.

Okereke. Possible Health Implications Associated with Cosmetics: A Review. Sci J Public Heal. 2015;3(5):58.

Gonçalves S, Gaivão I. Natural ingredients common in the Trás-os-montes region (Portugal) for use in the cosmetic industry: A review about chemical composition and antigenotoxic properties. Molecules. 2021;26(17).

Astuti A, Fitri N. Formulasi Serum Anti-Aging Minyak Atsiri Lada Hitam (Piper Nigrum L.) dan Uji Aktivitas Antioksidan Menggunakan Metode DPPH. Asian J Innov Entrep. 2020;5(1):1–11.

Sumaiyah, Leisyah BM. The effect of antioxidant of grapeseed oil as skin anti-aging in nanoemulsion and emulsion preparations. Rasayan J Chem. 2019;12(3):1185–94.

Garavaglia J, Markoski MM, Oliveira A, Marcadenti A. Grape seed oil compounds: Biological and chemical actions for health. Nutr Metab Insights. 2016;9:59–64.

Vanstone N, Moore A, Martos P, Neethirajan S. Detection of the adulteration of extra virgin olive oil by near-infrared spectroscopy and chemometric techniques. Food Qual Saf. 2018;2(4):189–98.

Riyanta AB, Riyanto S, Lukitaningsih E, Rohman A. Analysis of sunflower oil in ternary mixture with grapeseed oil and candlenut oil in the ternary mixture system using ftir spectroscopy and chemometrics. Food Res. 2020;4(5):1726–31.

Dzulfianto A, Riswanto FDO, Rohman A. The employment of UV-spectroscopy combined with multivariate calibration for analysis of paracetamol, propyphenazone and caffeine. Indones J Pharm. 2017;28(4):191–7.

Huang F, Song H, Guo L, Guang P, Yang X, Li L, et al. Detection of adulteration in Chinese honey using NIR and ATR-FTIR spectral data fusion. Spectrochim Acta - Part A Mol Biomol Spectrosc. 2020;235:1–8.

Bayne CK, Haswell SJ. Practical Guide to Chemometrics. Vol. 37, Technometrics. 1995. 230 p.

Hamdan MR, Ismail Z, Ahmad MN. Assessment of Herbal Medicines by Chemometrics - Assisted Interpretation of FTIR Spectra Assessment of Herbal Medicines by Chemometrics – Assisted Interpretation of FTIR Spectra. 2004;(May 2014).

Calvini R, Ulrici A, Amigo JM. Practical comparison of sparse methods for classification of Arabica and Robusta coffee species using near infrared hyperspectral imaging. Chemom Intell Lab Syst. 2015;146(2015):503–11.

Riswanto FDO, Windarsih A, Putri DCA, Gani MR. An Integrated Authentication Analysis of Citrus aurantium L . Essential Oil Based on FTIR Spectroscopy and Chemometrics with Tuning Parameters. Indones J Pharm. 2023;34(2):205–17.

Nurrulhidayah AF, Che Man YB, Al-Kahtani HA, Rohman A. Application of FTIR spectroscopy coupled with chemometrics for authentication of Nigella sativa seed oil. Spectroscopy. 2011;25(5):243–50.

Amit, Jamwal R, Kumari S, Dhaulaniya AS, Balan B, Singh DK. Application of ATR-FTIR spectroscopy along with regression modelling for the detection of adulteration of virgin coconut oil with paraffin oil. LWT - Food Sci Technol. 2020;118:108754. 10.1016/j.lwt.2019.108754

Rohman A, Che Man YB. Fourier transform infrared (FTIR) spectroscopy for analysis of extra virgin olive oil adulterated with palm oil. Food Res Int. 2010;43:886–892.

Rohman A, Setyaningrum DL, Riyanto S. FTIR Spectroscopy Combined with Partial Least Square for Analysis of Red Fruit Oil in Ternary Mixture System. Int J Spectrosc. 2014;2014:1–5. 10.1155/2014/785914

Rohart F, Gautier B, Singh A, Lê Cao KA. mixOmics: An R package for ‘omics feature selection and multiple data integration. PLoS Comput Biol. 2017;13(11):1–19.

Cebi N, Taylan O, Abusurrah M, Sagdic O. Detection of orange essential oil, isopropyl myristate, and benzyl alcohol in lemon essential oil by ftir spectroscopy combined with chemometrics. Foods. 2021;10(27):1–14.